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首页 > 报刊文摘 > Ligand chemistry of alkylselenolates: an experimental and DFT study of the formation and structural characterization of [PtCl2-x(SeR)x(PPh3)2] (x = 1, 2; R = tBu, nBu)

Ligand chemistry of alkylselenolates: an experimental and DFT study of the formation and structural characterization of [PtCl2-x(SeR)x(PPh3)2] (x = 1, 2; R = tBu, nBu)

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is-[Pt(SeR)2(PPh3)2] [R?=?tBu (1), nBu (2)] can be synthesized by the reaction of RSeLi with cis-[PtCl2(PPh3)2] in a molar ratio of 2:1. The reaction of equimolar amounts of cis-[PtCl2(PPh3)2] and RSeLi (R?=?tBu, nBu) produces a mixture containing cis-[Pt(SeR)2(PPh3)2] and [PtCl(SeR)(PPh3)2] [R?=?



出版机构:Taylor & Francis刊物名称:Main Group Chemistry
出版时间:2005
ISSN:1024-1221
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