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Two antimony germanates formulated as [(enH2)2.5][SbGe8O18(OH)4] (1) (en=ethylenediamine) and Sb4Ge3O12 (2) have been solvothermally synthesized and structurally characterized. Compound 1 represents the first organic containing microporous antimony germanate with three-dimensional (3D) channels. 出版机构:Elsevier Science 刊物名称:Inorganic Chemistry Communications 出版时间:2010 ISSN:1387-7003 数据源:报刊文摘
embly of Cd(II) nitrate with a novel tripyridyltriazole building block 3-(2-pyridyl)-4,5-bis(4-pyridyl)-1,2,4-triazole (L 1 ) and pseudohalide anion dicyanamide (dca) or azide (N3) yields two coordination polymers {[Cd(L 1 )2(dca)2](H2O)2} n (1) and {[Cd2(L 1 )(?1,1-N3)2(?1,3-N3)(N3)](H2O)1. 出版机构:Elsevier Science 刊物名称:Inorganic Chemistry Communications 出版时间:2010 ISSN:1387-7003 数据源:报刊文摘
Three one-dimensional coordination polymers, namely [ZnL 2(NO3)2] n (1), [CdL 2(NO3)2] n (2) and {[ZnL 2(H2O)2](ClO4)2?2L?2(H2O)} n (3), have been successfully synthesized based on a new unsymmetrical oxadiazole bridging ligand 2-[2-((3-pyridyl)methoxy)phenyl]-5-[(4-pyridyl)]-1,3,4-oxadiazole (L). 出版机构:Elsevier Science 刊物名称:Inorganic Chemistry Communications 出版时间:2010 ISSN:1387-7003 数据源:报刊文摘
mong the sixteen dioxidovanadium(V) complexes of the type (alkyl amineH+) [VO2(benzoyl hydrazone)]? reported here, the H-bonded centrosymmetric dimeric dioxidovanadium(V) complexes have been found to exist in the solid state only with diethylamine and piperidine. 出版机构:Elsevier Science 刊物名称:Inorganica Chimica Acta 出版时间:2010 ISSN:0020-1693 数据源:报刊文摘
eries of metal complexes have been prepared using two similar ketiminato ligands, ArL1 (([RN(H)(C(Me))2C(Me)O], ((R=2,6-diisopropylphenyl (Dipp) or 2,6-dimethylphenyl, (Dmp)) and the less bulky, multidentate molecule L2, ([RN(H)C(Me)CHC(Me)O] (R=C2H4NEt2)). 出版机构:Elsevier Science 刊物名称:Inorganica Chimica Acta 出版时间:2010 ISSN:0020-1693 数据源:报刊文摘
The polymeric complex, [Cu(abt)]? shows unique tetrahedral connectivity and ? reduced to the copper?sulfur arrangement ? close structural resemblance to the double-layer lattice of black phosphorus.A copper(I) complex of 2-aminobenzenethiol, [Cu(abt)]? (1), has been synthesized and characterized. 出版机构:Elsevier Science 刊物名称:Inorganica Chimica Acta 出版时间:2010 ISSN:0020-1693 数据源:报刊文摘
It crystallizes in the monoclinic space group P21/m(no. 11) with two formula units in the unit cell with dimensions of a = 813.21(6) pm, b = 1146.13(9) pm, c = 942.86(7) pm and ? = 107.504(5) ?. As the dominating structural feature {ZCe4}9. 出版机构:WILEY‐VCH Verlag 刊物名称:Zeitschrift für anorganische und allgemeine Chemie 出版时间:2010 ISSN:0044-2313 数据源:报刊文摘
This communication summarizes the important points made in each contribution. They show that there remain issues in the cheminformatic handling of tautomers and predicting the relative energies of various tautomers.
出版机构:Springer Netherlands 刊物名称:Journal of Computer-Aided Molecular Design 出版时间:2010 ISSN:0920-654X 数据源:报刊文摘
Two new salts based on [Ni(mnt)2]? or [Cu(mnt)2]2? anion, [FBzTPP][Ni(mnt)2](1) and [FBzTPP]2[Cu(mnt)2](2) ([FBzTPP]+ =1-(4?-fluorobenzyl)triphenylphosphinium, mnt2? =maleonitriledithiolate) have been investigated, and 1 exhibits a spin? 出版机构:Elsevier Science 刊物名称:Inorganica Chimica Acta 出版时间:2010 ISSN:0020-1693 数据源:报刊文摘
The reactivity of 1,3-diketones toward 3-aminophenylboronic acid was evaluated, spectroscopic analysis showed the formation of heterocyclic six-membered boron compounds. 出版机构:Elsevier Science 刊物名称:Inorganica Chimica Acta 出版时间:2010 ISSN:0020-1693 数据源:报刊文摘
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