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Synthesis, crystal structure and properties of two antimony germanate compounds

Two antimony germanates formulated as [(enH2)2.5][SbGe8O18(OH)4] (1) (en=ethylenediamine) and Sb4Ge3O12 (2) have been solvothermally synthesized and structurally characterized. Compound 1 represents the first organic containing microporous antimony germanate with three-dimensional (3D) channels.

出版机构:Elsevier Science

刊物名称:Inorganic Chemistry Communications

出版时间:2010

ISSN:1387-7003

数据源:报刊文摘

Anion-directed assembly of two fluorescent Cd(II) coordination polymers with a versatile multidentate N-donor building block 3-(2-pyridyl)-4,5-bis(4-pyridyl)-1,2,4-triazole

embly of Cd(II) nitrate with a novel tripyridyltriazole building block 3-(2-pyridyl)-4,5-bis(4-pyridyl)-1,2,4-triazole (L 1 ) and pseudohalide anion dicyanamide (dca) or azide (N3) yields two coordination polymers {[Cd(L 1 )2(dca)2](H2O)2} n (1) and {[Cd2(L 1 )(?1,1-N3)2(?1,3-N3)(N3)](H2O)1.

出版机构:Elsevier Science

刊物名称:Inorganic Chemistry Communications

出版时间:2010

ISSN:1387-7003

数据源:报刊文摘

Coordination-directed one-dimensional coordination polymers generated from a new unsymmetrical oxadiazole bridging ligand and transition metal ions

Three one-dimensional coordination polymers, namely [ZnL 2(NO3)2] n (1), [CdL 2(NO3)2] n (2) and {[ZnL 2(H2O)2](ClO4)2?2L?2(H2O)} n (3), have been successfully synthesized based on a new unsymmetrical oxadiazole bridging ligand 2-[2-((3-pyridyl)methoxy)phenyl]-5-[(4-pyridyl)]-1,3,4-oxadiazole (L).

出版机构:Elsevier Science

刊物名称:Inorganic Chemistry Communications

出版时间:2010

ISSN:1387-7003

数据源:报刊文摘

Synthesis, structure and solution chemistry of dioxidovanadium(V) complexes with a family of hydrazone ligands. Evidence of formation of centrosymmetric dimers via H-bonds in the solid state

mong the sixteen dioxidovanadium(V) complexes of the type (alkyl amineH+) [VO2(benzoyl hydrazone)]? reported here, the H-bonded centrosymmetric dimeric dioxidovanadium(V) complexes have been found to exist in the solid state only with diethylamine and piperidine.

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘

Ketiminato and ketimine Co, Eu, Cu and Fe complexes

eries of metal complexes have been prepared using two similar ketiminato ligands, ArL1 (([RN(H)(C(Me))2C(Me)O], ((R=2,6-diisopropylphenyl (Dipp) or 2,6-dimethylphenyl, (Dmp)) and the less bulky, multidentate molecule L2, ([RN(H)C(Me)CHC(Me)O] (R=C2H4NEt2)).

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘

A metallopolymer, [Cu(abt)]∞ (abt, 2-aminobenzenethiol) with novel structural patterns resembling black phosphorus

The polymeric complex, [Cu(abt)]? shows unique tetrahedral connectivity and ? reduced to the copper?sulfur arrangement ? close structural resemblance to the double-layer lattice of black phosphorus.A copper(I) complex of 2-aminobenzenethiol, [Cu(abt)]? (1), has been synthesized and characterized.

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘

A New Example of the Structure Type A2[{Z2R4}X9]: Synthesis and Crystal Structure of Na2[{(ON)Ce4}Cl9] Dedicated to Professor Gerd Becker on the Occasion of His 70th Birthday

It crystallizes in the monoclinic space group P21/m(no. 11) with two formula units in the unit cell with dimensions of a = 813.21(6) pm, b = 1146.13(9) pm, c = 942.86(7) pm and ? = 107.504(5) ?. As the dominating structural feature {ZCe4}9.

出版机构:WILEY‐VCH Verlag

刊物名称:Zeitschrift für anorganische und allgemeine Chemie

出版时间:2010

ISSN:0044-2313

数据源:报刊文摘

Overview of the perspectives devoted to tautomerism in molecular design

This communication summarizes the important points made in each contribution. They show that there remain issues in the cheminformatic handling of tautomers and predicting the relative energies of various tautomers.

出版机构:Springer Netherlands

刊物名称:Journal of Computer-Aided Molecular Design

出版时间:2010

ISSN:0920-654X

数据源:报刊文摘

Two salts containing bis(maleonitriledithiolate)nickel(III)/copper(II) anion and substituted benzyltriphenylphosphinium: Syntheses, crystal structures and magnetic properties

Two new salts based on [Ni(mnt)2]? or [Cu(mnt)2]2? anion, [FBzTPP][Ni(mnt)2](1) and [FBzTPP]2[Cu(mnt)2](2) ([FBzTPP]+ =1-(4?-fluorobenzyl)triphenylphosphinium, mnt2? =maleonitriledithiolate) have been investigated, and 1 exhibits a spin?

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘

Boron complexes derived from the condensation reaction of 3-aminophenylboronic acid and 1,3-diketones

The reactivity of 1,3-diketones toward 3-aminophenylboronic acid was evaluated, spectroscopic analysis showed the formation of heterocyclic six-membered boron compounds.

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘