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Kinetics and mechanism of oxidation of acetanilide by quinquevalent vanadium in acid medium

SummaryThe kinetics of the oxidation of acetanilide with vanadium(V) in sulphuric acid medium at constant ionic strength has been studied. The reaction is first order with oxidant. The order of reaction in acetanilide varies from one to zero.

出版机构:Springer Vienna

刊物名称:Monatshefte fuer Chemie/Chemical Monthly

出版时间:1990

ISSN:0026-9247

数据源:报刊文摘

Thermal and Oxidative Transformations of Polycyclohexadiene in the Solid Phase and Solution

The paper deals with the investigation of polycyclohexadiene oxidation mechanism in the solid phase and solution so as its inhibition. The schemes of these processes are proposed and kinetic parameters have been determined.

出版机构:Taylor & Francis

刊物名称:International Journal of Polymeric Materials

出版时间:1990

ISSN:0091-4037

数据源:报刊文摘

Degradation and Stabilization of Epichlorohydrin Elastomers

Thermo-oxidative destruction of epichlorohydrin elastomers by methods of IR- and ESR-spectroscopy. Variation of physico-mechanical properties has been also studied. Antioxidants are proposed for these polymers. The mechanism of oxidation is discussed.

出版机构:Taylor & Francis

刊物名称:International Journal of Polymeric Materials

出版时间:1990

ISSN:0091-4037

数据源:报刊文摘

Kinetics and Mechanism of Oxidation of Mono- and Polyacetals

Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70?C, 15-16 hr) leads to the formation monoethers of the corresponding glycols with 68-90% selectivity.

出版机构:Taylor & Francis

刊物名称:International Journal of Polymeric Materials

出版时间:1990

ISSN:0091-4037

数据源:报刊文摘

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