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Synthesis, structural characterization and catalytic activity of a palladium(II) complex bearing a new ditopic thiophene-N-heterocyclic carbene ligand

Reaction of the new 1-(2-thienylmethyl)-3-methylbenzimidazolium salt 2 with Pd(OAc)2 afforded the first thiophene-functionalized bis(benzimidazolin-2-ylidene) Pd(II) complex (cis-3) as a mixture of rare cis?syn and cis?anti rotamers.

出版机构:Elsevier Science

刊物名称:Inorganica Chimica Acta

出版时间:2010

ISSN:0020-1693

数据源:报刊文摘

Electrospray mass spectrometric study of homogeneous catalytic system Pd(CF3COO)2-Ph2P(CH2)3PPh2-MeOH/Me2CO-H2O for copolymerization of ethylene and carbon monoxide

AbstractThe catalytic system Pd(CF3COO)2-Ph2P(CH2)3PPh2-MeOH/Me2CO was studied by electrospray mass spectrometry. The {[Pd(dPPP)2]2+ [(dppp)2Pd(CF3COO)]+, [(dppp)Pd(CF3COO)]+, and [(dppp)Pd(CF3COO)2Pd(dppp)]2+} cations were found in the system.

出版机构:Springer US

刊物名称:Russian Chemical Bulletin

出版时间:1996

ISSN:1066-5285

数据源:报刊文摘

Ethylene and carbon monoxide copolymerization catalyzed by supported palladium catalyst

The kinetic regularities of the CO/C2H4 copolymerization catalyzed by (dppp)Pd(TsO)2 (I) have been studied under homogeneous conditions and in slurry with supported catalysts I/support (support: polyketone or silica gel).

出版机构:Elsevier Science

刊物名称:Journal of Molecular Catalysis A: Chemical

出版时间:2010

ISSN:1381-1169

数据源:报刊文摘

Direct hydroxylation of benzene to phenol in a novel microstructured membrane reactor with distributed dosing of hydrogen and oxygen

The direct conversion of benzene to phenol in the gas phase in a palladium membrane reactor has been investigated with deviating results by various researchers in recent years. Experiments carried out in Japan showed high phenol yields up to 23% .

出版机构:Elsevier Science

刊物名称:Separation and Purification Technology

出版时间:2010

ISSN:1383-5866

数据源:报刊文摘

Strain and resistivity of PdH x at hydrogen composition x >0.8

Measurements of lattice expansion and electrical resistance versus hydrogen concentration, x =H/Pd, in a continuous range of stoichiometry [0? x ?1.16] in the PdH x stretched system have been performed.

出版机构:Elsevier Science

刊物名称:Journal of Alloys and Compounds

出版时间:2010

ISSN:0925-8388

数据源:报刊文摘

Low frequency internal friction spectra of Cu0·81 Pd0·19 alloy

AbstractResults on the internal friction of disordered and partially ordered Cu0?81Pd0?19 alloy in the temperature range 160–300 K and frequency range 1–2 Hz are reported. All the peaks are classified into three groups.

出版机构:Indian Academy of Sciences

刊物名称:Bulletin of Materials Science

出版时间:1988

ISSN:0250-4707

数据源:报刊文摘

Metal–support interactions in Pt/Al2O3 and Pd/Al2O3 catalysts for CO oxidation

Platinum and palladium catalysts supported on �-Al2O3 were studied by XRD, UV vis DRS, HRTEM, TPR-H2, XPS together with measurements of their catalytic properties.

出版机构:Elsevier Science

刊物名称:Applied Catalysis B: Environmental

出版时间:2010

ISSN:0926-3373

数据源:报刊文摘